Clays and Clay Minerals, Vol. 58, No. 2, 188–204, 2010.
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Authors
Trindade, Maria Jose
Dias, Maria Isabel
Coroado, Joao
Rocha, Fernando
Issue Date
2010
Type
Article
Language
Keywords
Periodicals , Geology , Algarve Basin , Clays , Firing Tests , High-temperature Minerals , Mineral Transformations , X-ray Diffraction
Alternative Title
Firing Tests On Clay-rich Raw Materials From The Algarve Basin (southern Portugal): Study Of Mineral Transformations With Temperature
Abstract
In cases where the provenance of raw materials used in the manufacture of local archeological ceramics is of interest, a detailed study of thermal transformations of minerals may be useful. The purpose of this study was to measure mineralogical transformations of different types of clays obtained during experimental firing runs, carried out at different temperatures, with the main goal of establishing Algarve reference groups based on the composition of raw material and high-temperature mineralogy, which may be compared with ceramics in studies of provenance. Eleven samples of clay-rich raw materials from the Algarve Basin (southern Portugal) were fired to temperatures ranging from 300 to 1100ºC in increments of 100ºC under oxidizing conditions. These were chosen to have variable chemical and mineralogical compositions, representing the main compositional range of the clay deposits from the region. Mineralogical and geochemical characterizations of the original clays were carried out by X-ray diffraction (XRD) and X-ray fluorescence (XRF), respectively. Mineral transformations on the fired products were also studied by XRD. Three groups of clays were distinguished according to the type of neoformed high-temperature minerals: (1) non-calcareous clays; (2) clays containing calcite as the only carbonate; and (3) clays with dolomite or dolomite + calcite. Firing of non-calcareous clays produced mullite at 1100-1200ºC. Gehlenite and wollastonite formed by firing calcite-rich clays above 900ºC, accompanied by anorthite or larnite in samples with small or large calcite contents, respectively. Firing of dolomite-rich clays at temperatures >900ºC yielded a member of the gehlenite-a˚kermanite group and diopside. Anorthite, enstatite, periclase, forsterite, and monticellite may also form in the firing products.
Description
gsccm58205-tri.pdf : 1,113KB
Citation
Clays and Clay Minerals, Vol. 58, No. 2, 188–204, 2010.
Publisher
The Clay Minerals Society
License
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